Carbonaceous chondrites as analogs for the composition and alteration of Ceres          下载免费PDF全文

Harry Y. McSween Jr.  Joshua P. Emery  Andrew S. Rivkin  Michael J. Toplis  Julie C. Castillo‐Rogez  Thomas H. Prettyman  M. Cristina De Sanctis  Carle M. Pieters  Carol A. Raymond  Christopher T. Russell 《Meteoritics & planetary science》2018,53(9):1793-1804

The mineralogy and geochemistry of Ceres, as constrained by Dawn's instruments, are broadly consistent with a carbonaceous chondrite (CM/CI) bulk composition. Differences explainable by Ceres’s more advanced alteration include the formation of Mg‐rich serpentine and ammoniated clay; a greater proportion of carbonate and lesser organic matter; amounts of magnetite, sulfide, and carbon that could act as spectral darkening agents; and partial fractionation of water ice and silicates in the interior and regolith. Ceres is not spectrally unique, but is similar to a few other C‐class asteroids, which may also have suffered extensive alteration. All these bodies are among the largest carbonaceous chondrite asteroids, and they orbit in the same part of the Main Belt. Thus, the degree of alteration is apparently related to the size of the body. Although the ammonia now incorporated into clay likely condensed in the outer nebula, we cannot presently determine whether Ceres itself formed in the outer solar system and migrated inward or was assembled within the Main Belt, along with other carbonaceous chondrite bodies.  相似文献   

Ultraviolet spectroscopy of Asteroid (4) Vesta     

Jian-Yang Li  Dennis Bodewits  Lori M. Feaga  Wayne Landsman  Michael F. A’Hearn  Max J. Mutchler  Christopher T. Russell  Lucy A. McFadden  Carol A. Raymond 《Icarus》2011,216(2):640-649

We report a comprehensive review of the UV–visible spectrum and rotational lightcurve of Vesta combining new observations by Hubble Space Telescope and Swift Gamma-ray Burst Observatory with archival International Ultraviolet Explorer observations. The geometric albedos of Vesta from 220 nm to 953 nm are derived by carefully comparing these observations from various instruments at different times and observing geometries. Vesta has a rotationally averaged geometric albedo of 0.09 at 250 nm, 0.14 at 300 nm, 0.26 at 373 nm, 0.38 at 673 nm, and 0.30 at 950 nm. The linear spectral slope as measured between 240 and 320 nm in the ultraviolet displays a sharp minimum near a sub-Earth longitude of 20°, and maximum in the eastern hemisphere. This is consistent with the longitudinal distribution of the spectral slope in the visible wavelength. The photometric uncertainty in the ultraviolet is ∼20%, and in the visible wavelengths it is better than 10%. The amplitude of Vesta’s rotational lightcurves is ∼10% throughout the range of wavelengths we observed, but is smaller at 950 nm (∼6%) near the 1-μm band center. Contrary to earlier reports, we found no evidence for any difference between the phasing of the ultraviolet and visible/near-infrared lightcurves with respect to sub-Earth longitude. Vesta’s average spectrum between 220 and 950 nm can well be described by measured reflectance spectra of fine particle howardite-like materials of basaltic achondrite meteorites. Combining this with the in-phase behavior of the ultraviolet, visible, and near-infrared lightcurves, and the spectral slopes with respect to the rotational phase, we conclude that there is no global ultraviolet/visible reversal on Vesta. Consequently, this implies a lack of global space weathering on Vesta, as previously inferred from visible–near-infrared data.  相似文献   

Human and Environmental Factors Affect Patterns of Crop Diversity in an Ethiopian Highland Agroecosystem     

Leah H. Samberg  Carol Shennan  Erika S. Zavaleta 《The Professional geographer》2013,65(3):395-408

The Ethiopian highlands are a center of diversity for numerous globally important crops. Heterogeneous landscapes, traditional agricultural practices, and inaccessibility have created and maintained diverse subsistence agroecosystems. We surveyed sixty-three farms in twelve communities of the Gamo highlands and found high levels of on-farm diversity of crop species and varieties. The extent and nature of this diversity are related to both ecological factors, namely elevation, and anthropogenic factors such as land-use history, accessibility to markets and extension, and strength and scale of farmer exchange networks. These human landscape features have the potential to both enhance and mediate effects of elevation and other environmental factors on crop diversity. The interaction of environmental and anthropogenic forces on the diversity of crops grown by farmers affects the strategies farmers employ to adapt their farming to changing conditions.  相似文献   

Arsenic attenuation in tailings at a former Cu–W–As mine,SW Finland     

Annika Parviainen  Matthew B.J. Lindsay  Rafael Pérez-López  Blair D. Gibson  Carol J. Ptacek  David W. Blowes  Kirsti Loukola-Ruskeeniemi 《Applied Geochemistry》2012

Nearly half a century after mine closure, release of As from the Ylöjärvi Cu–W–As mine tailings in groundwater and surface water run-off was observed. Investigations by scanning electron microscopy (SEM), electron microprobe analysis (EMPA), synchrotron-based micro-X-ray diffraction (μ-XRD), micro-X-ray absorption near edge structure (μ-XANES) and micro-extended X-ray absorption fine structure (μ-EXAFS) spectroscopy, and a sequential extraction procedure were performed to assess As attenuation mechanisms in the vadose zone of this tailings deposit. Results of SEM, EMPA, and sequential extractions indicated that the precipitation of As bearing Fe(III) (oxy)hydroxides (up to 18.4 wt.% As₂O₅) and Fe(III) arsenates were important secondary controls on As mobility. The μ-XRD, μ-XANES and μ-EXAFS analyses suggested that these phases correspond to poorly crystalline and disordered As-bearing precipitates, including arsenical ferrihydrite, scorodite, kaňkite, and hydrous ferric arsenate (HFA). The pH within 200 cm of the tailings surface averaged 5.7, conditions which favor the precipitation of ferrihydrite. Poorly crystalline Fe(III) arsenates are potentially unstable over time, and their transformation to ferrihydrite, which contributes to As uptake, has potential to increase the As adsorption capacity of the tailings. Arsenic mobility in tailings pore water at the Ylöjärvi mine will depend on continued arsenopyrite oxidation, dissolution or transformation of secondary Fe(III) arsenates, and the As adsorption capacity of Fe(III) (oxy)hydroxides within this tailings deposit.  相似文献   

Variation in river multi-element chemistry related to bedrock buffering: an example from the Adirondack region of northern New York, USA     

Jeffrey Chiarenzelli  Robin Lock  Carol Cady  Adria Bregani  Benn Whitney 《Environmental Earth Sciences》2012,67(1):189-204

Water from four north-flowing rivers (Oswegatchie, Grasse, Raquette, and West Branch of the St. Regis) traversing three distinct geologic terranes (Adirondack Highlands, Adirondack Lowlands, St. Lawrence Valley), originating in the acidified northern Adirondack region, display rapid spatial changes in downriver multi-element chemistry and physical parameters. Downriver, most soluble elements increase (Ba, Ca, Cu, K, Mg, Na, Rb, S, and Sr) while statistically significant decreases in insoluble elements (Al, Ce, Dy, Er, Fe, Gd, La, Mn, Nd, Pr, and Y) also occur. Lithium, Si, and Zr did not show a consistent increasing or decreasing trend. Concentrations of most elements measured on June 5, 2008 were greater than 7?weeks later; however, greater discharge and lower pH enhanced Al concentrations occurred during the later sampling date. Elemental ratios track changes in lithology, anthropogenic influence, and pH. The Raquette River shows the least variation in elemental concentrations because of storage in numerous hydropower reservoirs and has non-detectable concentrations of some redox sensitive elements such as Co, Ni, and V. Oswegatchie tributaries display similar geochemical trends dependent upon their location and local bedrock and show geochemical trends along the trunks of major rivers that are also evident in smaller drainage basins. Comparison with analytical results from the Western Adirondack Stream Survey also indicates acidification is prevalent in the Adirondack Highlands, particularly in the Oswegatchie headwaters during periods of high flow, but acidity is rapidly buffered downriver due to interaction with marble in the Adirondack Lowlands.  相似文献   

Challenging the boundaries of entrepreneurship: The spatialities and practices of UK ‘Mumpreneurs’     

Carol Ekinsmyth 《Geoforum》2011,42(1):104-114

This paper examines the spatialities and practices of an illustrative sample of UK mumpreneurs, a sub-group of female entrepreneurs who operate at the interface between paid work and motherhood, who are increasing numerically, and who are carving for themselves, a sub-culture of entrepreneurship. They have great policy-importance, not least because the UK government has recognised mothers as a group who need to be encouraged into business ownership. Employing mixed methods with emphasis on qualitative approaches, the research findings suggest that policy makers need to understand better some key aspects of this entrepreneurial activity before their interventions can be effective.  相似文献   

Associated terrestrial and marine fossils in the late-glacial Presumpscot Formation, southern Maine, USA, and the marine reservoir effect on radiocarbon ages   总被引：1，自引：0，他引：1  

Woodrow B. Thompson  Carol B. Griggs  Norton G. Miller  Robert E. Nelson  Thomas K. Weddle  Taylor M. Kilian   《Quaternary Research》2011,75(3):552-565

Excavations in the late-glacial Presumpscot Formation at Portland, Maine, uncovered tree remains and other terrestrial organics associated with marine invertebrate shells in a landslide deposit. Buds of Populus balsamifera (balsam poplar) occurred with twigs of Picea glauca (white spruce) in the Presumpscot clay. Tree rings in Picea logs indicate that the trees all died during winter dormancy in the same year. Ring widths show patterns of variation indicating responses to environmental changes. Fossil mosses and insects represent a variety of species and wet to dry microsites. The late-glacial environment at the site was similar to that of today's Maine coast. Radiocarbon ages of 14 tree samples are 11,907 ± 31 to 11,650 ± 50 ¹⁴C yr BP. Wiggle matching of dated tree-ring segments to radiocarbon calibration data sets dates the landslide occurrence at ca. 13,520 + 95/−20 cal yr BP. Ages of shells juxtaposed with the logs are 12,850 ± 65 ¹⁴C yr BP (Mytilus edulis) and 12,800 ± 55 ¹⁴C yr BP (Balanus sp.), indicating a marine reservoir age of about 1000 yr. Using this value to correct previously published radiocarbon ages reduces the discrepancy between the Maine deglaciation chronology and the varve-based chronology elsewhere in New England.  相似文献   

Plant Cover,Herbivory, and Resiliency in a Cape Cod Salt Marsh: Multi-year Responses and Recovery Following Manipulation of Nutrients and Competition     

Carol S. Rietsma  Rita Oliveira Monteiro  Ivan Valiela 《Estuaries and Coasts》2011,34(1):198-210

To assess responses and recovery of salt marsh grass species, we manipulated external nutrient supply and removed shoots of Spartina alterniflora or Spartina patens from fertilized and control plots in a Massachusetts marsh. The pulse-and-recovery experiment included treatments for 5 years, and recovery for an additional 7 years. Responses of these potential competitors sensitively depended on local contingencies of elevation and nutrient dose, and, moreover, the differences in outcomes were emphasized at longer time scales. Local contingencies became manifest as differences in responsiveness and resiliency of the different grass species, with differing time courses and longer-term outcomes as to what species were present. These features might explain the diverse results obtained in shorter-term salt marsh experiments, and provide a view of the complex suite of species-specific and external environmental variables that may control competitive interactions in general.  相似文献   

Global photometric properties of Asteroid (4) Vesta observed with Dawn Framing Camera     

Jian-Yang Li  Lucille Le Corre  Stefan E. Schröder  Vishnu Reddy  Brett W. Denevi  Bonnie J. Buratti  Stefano Mottola  Martin Hoffmann  Pablo Gutierrez-Marques  Andreas Nathues  Christopher T. Russell  Carol A. Raymond 《Icarus》2013

Dawn spacecraft orbited Vesta for more than one year and collected a huge volume of multispectral, high-resolution data in the visible wavelengths with the Framing Camera. We present a detailed disk-integrated and disk-resolved photometric analysis using the Framing Camera images with the Minnaert model and the Hapke model, and report our results about the global photometric properties of Vesta. The photometric properties of Vesta show weak or no dependence on wavelengths, except for the albedo. At 554 nm, the global average geometric albedo of Vesta is 0.38 ± 0.04, and the Bond albedo range is 0.20 ± 0.02. The bolometric Bond albedo is 0.18 ± 0.01. The phase function of Vesta is similar to those of S-type asteroids. Vesta’s surface shows a single-peaked albedo distribution with a full-width-half-max ∼17% relative to the global average. This width is much smaller than the full range of albedos (from ∼0.55× to >2× global average) in localized bright and dark areas of a few tens of km in sizes, and is probably a consequence of significant regolith mixing on the global scale. Rheasilvia basin is ∼10% brighter than the global average. The phase reddening of Vesta measured from Dawn Framing Camera images is comparable or slightly stronger than that of Eros as measured by the Near Earth Asteroid Rendezvous mission, but weaker than previous measurements based on ground-based observations of Vesta and laboratory measurements of HED meteorites. The photometric behaviors of Vesta are best described by the Hapke model and the Akimov disk-function, when compared with the Minnaert model, Lommel–Seeliger model, and Lommel–Seeliger–Lambertian model. The traditional approach for photometric correction is validated for Vesta for >99% of its surface where reflectance is within ±30% of global average.  相似文献   

Lithologic mapping of HED terrains on Vesta using Dawn Framing Camera color data     

Guneshwar Thangjam  Vishnu Reddy  Lucille Le Corre  Andreas Nathues  Holger Sierks  Harald Hiesinger  Jian‐Yang Li  Juan A. Sanchez  Christopher T. Russell  Robert Gaskell  Carol Raymond 《Meteoritics & planetary science》2013,48(11):2199-2210

The surface composition of Vesta, the most massive intact basaltic object in the asteroid belt, is interesting because it provides us with an insight into magmatic differentiation of planetesimals that eventually coalesced to form the terrestrial planets. The distribution of lithologic and compositional units on the surface of Vesta provides important constraints on its petrologic evolution, impact history, and its relationship with vestoids and howardite‐eucrite‐diogenite (HED) meteorites. Using color parameters (band tilt and band curvature) originally developed for analyzing lunar data, we have identified and mapped HED terrains on Vesta in Dawn Framing Camera (FC) color data. The average color spectrum of Vesta is identical to that of howardite regions, suggesting an extensive mixing of surface regolith due to impact gardening over the course of solar system history. Our results confirm the hemispherical dichotomy (east‐west and north‐south) in albedo/color/composition that has been observed by earlier studies. The presence of diogenite‐rich material in the southern hemisphere suggests that it was excavated during the formation of the Rheasilvia and Veneneia basins. Our lithologic mapping of HED regions provides direct evidence for magmatic evolution of Vesta with diogenite units in Rheasilvia forming the lower crust of a differentiated object.  相似文献